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Reductive amination secondary amine





This process is called reductive amination.
Chen, Synthesis, 2017,.
Hossein Ghafuri was born in Damavand, Iran, in 1974.1,2-Dichloroethane (DCE) is the preferred reaction solvent, but reactions can also be carried out in tetrahydrofuran and occasionally in acetonitrile.You may recall that NaBH4 is used for the reduction of aldehydes and ketones.In Organic Chemistry, San Jose State University, San Jose, California (19731975) and his.Direct treatment of benzylamine with an alkylating agent (e.g.Lett., 2007, 9, 267-270.If a molecule contains both an amine and a carbonyl, then it can cyclize to give a cyclic amine.NaBH4 can be a perfectly acceptable reducing agent for reductive amination.



Yokomatsu, Synthesis, 2014, 46, 455-464.
Sodium triacetoxyborohydride is a general, mild, and selective reducing agent for the reductive amination of various aldehydes and ketones.
While alkylation can happen multiple times on an amine, imines only form once on a given amine.
Note that the carbon attached to the nitrogen doesnt have a C-H bond.
Why use a weaker reducing agent?When drawing out the product of ring formation, I strongly advise counting and numbering your mes cadeaux de noël 2018 carbons.His research fields include green chemistry, sulfur chemistry and nanomagnets.For example, look at the synthesis of the tertiary amine below.Currently, he is Profosser in the Department of Chemistry Sharif University of Technology.



The solvent can be revovered and reused.

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